Título: The reaction of 2,3-dibromoindone with pyridine.
Autores: Redkevitch, Zenon.
Fecha: 1952
Publicador: McGill University - MCGILL
Fuente:
Tipo: Electronic Thesis or Dissertation
Tema: Chemistry.
Descripción: The aim of this work was to synthesize the 2,3-dibromo-inden-2-one-1 by the method of Roser; and to study the reaction of this compound with pyridine and with the three methyl-pyridines. Since it was known that the bromine atom in the 3- position of 2,3-dibromoindone could split off as a negative ion, one would expect the formation of a pyridinium salt. The pyridium salt would be expected to react with aniline in a manner similar to the ring opening reaction of zincke. It was hoped that the investigation of this reaction could offer additional knowledge concerning the reaction mechanism of the pyridine ring opening.[...]
Idioma: en