Two-electron mixed-valence complexes of rhodium may be supported by diphosphazane ligands (RN(PY2)2). Whereas diphosphazane ligands with strongly [pi]-acidic phosphine groups (Y = F, OCH2CF3) react with RhI starting materials to afford binuclear Rh20,II complexes, Rh20,II(MeN(PY)2)3X2(L) or Rh2"II(MeN(PY),)3X2 (X = Cl,…

by Neil William Van Dyke., Thesis (S.M.)--Massachusetts Institute of Technology, School of Architecture and Planning, Program in Media Arts and Sciences, 2000., "February 2000.", Includes bibliographical references (p. 87-91).

We strain our eyes, cramp our necks, and destroy our hands trying to interact with computer on their terms. At the extreme, we strap on devices and weigh ourselves down with cables trying to re-create a sense of place inside…

Knowledge of how groups of people interact is important in many disciplines, e.g. organizational behavior, social network analysis, knowledge management and ubiquitous computing. Existing studies of social network interactions have either been restricted to online communities, where unambiguous measurements about…

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The Triple β-Spiral is a novel protein structure that plays a role in viral attachment and pathogenesis. At present, there are two Triple β-Spiral structures with solved crystallographic coordinates - one from Adenovirus and the other from Reovirus. There is…

In this thesis, the opportunities and challenges involved in applying natural language processing techniques to the control of unmanned aerial vehicles (UAVs) are addressed. The problem of controlling an unmanned aircraft via natural language inputs is formulated as a feedback…

The quality of higher education has been a growing concern in the United States and United Kingdom. There have been no notable improvements in the education system until the last few years. Considerable transformation in the higher education arena has…

Direct wafer bonding has emerged as an important technology in the manufacture of silicon-on-insulator substrates (SOI), microelectromechanical systems (MEMS), and three-dimensional integrated circuits (3D IC's). While the process is currently employed in applications such as these, a lack of knowledge…

The contribution of this thesis is to provide a tractable framework for supply chains and revenue management problems subject to uncertainty that gives insight into the structure of the optimal policy and requires little knowledge of the underlying probability distributions.…