| Título: | Solution of Nonlinear Polarization Boundary Conditions |
| Autores: |
E. Chisholm; Oak Ridge National Laboratory L.J. Gray; Oak Ridge National Laboratory G.E. Giles; Oak Ridge National Laboratory |
| Fecha: | 2007-10-25 |
| Publicador: | Electronic journal of boundary elements |
| Fuente: |
 |
| Tipo: | |
| Tema: | No aplica |
| Descripción: | An efficient algorithm for solving multiple reaction electrochemical polarization equations is presented. The boundary integral formulation for the electric field (Laplace equation) conveniently provides a direct relationship between potential and current at the electrode surfaces, which can then be coupled to the nonlinear polarization boundary conditions. As a consequence, a successful Gauss-Seidel type iteration, incorporating a nonlinear solve at each step, can be developed. Results are presented for the modeling multiple chemical reactions in an electrospray emitter tube. |
| Idioma: | Inglés |
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