| Título: | Use of 5-[2-Ethoxyquinazolone-3-yl]-2-phthalimidomethylthiadiazole in the Synthesis of N- and C-Glycosides via Amadori Rearra |
| Autores: | Darwish, Khalid M |
| Fecha: | 2011-12-02 |
| Publicador: | Chemestry and Materials Research |
| Fuente: |
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| Tipo: |
info:eu-repo/semantics/article Peer-reviewed Article info:eu-repo/semantics/publishedVersion |
| Tema: | No aplica |
| Descripción: | Synthesis of novel 5-[2- aminoquinazolin-4-one-3-yl]-2- phthalimidomethylthiadiazole   2 from  5-[2-ethoxyquinazolin-4-one-3-yl]-2-phthalamidomethylthiadiazole. The behavior of as a nitrogen nucleophile towards an ±-hydroxy-aldehyde,  such as glucose and formation of Amadori rearrangement product (ARP) that has had occurred during the course of reaction was discussed. Keywords: N-Glycosides, ±-bromoglucose, Amadori rearrangement, quinazolinone |
| Idioma: | Inglés |