| Título: | Mixed complexes of cobalt(III) with D-glucosamine and phenanthroline |
| Autores: |
Blasko, Andrei Bunton, Clifford A. Bunel, Sergio Moraga, Exequiel Ibarra, Carmen Parada, José |
| Fecha: |
2011-06-10 2011-06-10 1995 |
| Publicador: | Sociedad Chilena de Química |
| Fuente: |
Ver documento |
| Tipo: | Artículo de Revista |
| Tema: |
Cobalt(III) D-glucosamine Phenanthroline |
| Descripción: |
Artículo de publicación ISI Examination of 1H chemical shifts of a complex of D-glucosamine with bis-phenanthroline cobalt(III)shows that the dominant ∆-complex is formed from α-D-glucosamine. A molecular mechanics simulation of the structure of this complex indicates that the sugar residue is not markedly perturbed by complexation of Co(III) at the 1-alkoxide and 2-amino groups. The circular dichroism spectrum of the complex formed in solution agrees with that of the isolated material. |
| Idioma: | Inglés |