Título: NANOCOMPOSITES OF POLY(LACTIC ACID) REINFORCED WITH CELLULOSE NANOFIBRILS
Autores: Qu, Ping
Gao, Yuan
Wu, Guofeng
Zhang, Liping
Fecha: 2010-04-28
Publicador: Bioresources
Fuente:
Tipo: info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Tema: Cellulose whiskers; Poly(lactic acid); Interfacial interaction; Nanocomposite
Descripción: A chemo-mechanical method was used to prepare cellulose nanofibrils dispersed uniformly in an organic solvent. Poly(ethylene glycol) (PEG 1000) was added to the matrix as a compatibilizer to improve the interfacial interaction between the hydrophobic poly(lactic acid) (PLA) and the hydrophilic cellulose nanofibrils. The composites obtained by solvent casting methods from N,N-Dimethylacetamide (DMAc) were characterized by tensile testing machine, atomic force microscope (AFM), scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FT-IR). The tensile test results indicated that, by adding PEG to the PLA and the cellulose nanofibrils matrix, the tensile strength and the elongation rate increased by 56.7% and 60%, respectively, compared with the PLA/cellulose nanofibrils composites. The FT-IR analysis successfully showed that PEG improved the intermolecular interaction, which is based on the existence of inter-molecular hydrogen bonding among PLA, PEG, and cellulose nanofibrils.
Idioma: Inglés

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